Chemistry of the f-Block ElementsCRC Press, 2001/05/15 - 176 ページ This book, based on a lecture course which is given to final year undergraduates at Liverpool, illustrates the main features of f-block chemistry, along with some of the important applications, outlining the spectroscopic techniques which are commonly applied to complexes of the f-block elements. |
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actinide actinide complexes adducts alkene alkoxides alkyl analogues anhydrous anionic aqueous solution aryloxide atoms bis(cyclopentadienyl bulky C-H activation catalysts catalyzed Ce(IV Chapter characterized chelating Chem chiral compounds configuration contrast agents coordination chemistry coordination numbers Cp ligands crown ethers crystal field crystal structure cyclopentadienyl dimer donors electron emission enantioselective energy Eu3+ extraction f-block f-block elements formation Gd³ Gd3+ H₂O molecules halides homoleptic hydrides Inorg interaction ionic radius ions known lanthanide lanthanide alkoxides lanthanide complexes lanthanides and actinides laser Lewis acids Lewis bases ligands Ln³ Ln3+ LnCl LnCl3 luminescence macrocycle magnetic metathesis metathesis reactions monomeric NMR spectra NMR spectroscopy organolanthanide organometallic oxidation paramagnetic phosphido phosphine polymerization prepared protonolysis rare earth reactivity reduction resonance sensitive shown in Figure shown in Scheme shows silylamide solvent spectrum ẞ-diketonates stability constants stable steric synthesis thorium transition metal uranium uranocene X-ray