Handbook of Grignard ReagentsCRC Press, 1996/04/25 - 736 ページ This handbook provides the theoretical and practical information necessary to explore new applications for Grignard reagents on a day-to-day basis, presenting a comprehensive overview of current research activities in Grignard chemistry. This book surveys specific reactions and applications of Grignard reagents, organized by type of substrate and t |
目次
| 1 | |
| 9 | |
3 Preparation of Grignard Reagents from Olefins and Acetylenes | 23 |
4 Magnesium Activation | 53 |
5 Safe Handling Practices of Industrial Scale Grignard Reagents | 79 |
6 Wet Analyses of Grignard Reagents | 89 |
7 Infrared and Raman Spectroscopy | 93 |
8 Nuclear Magnetic Resonance Analyses of Grignard Reagents | 103 |
19 Nucleophilic Addition to Conjugated CarbonCarbon Multiple Bonds | 381 |
O S N | 391 |
21 Nucleophilic Addition to Organometallic Vinylidene and Allyl Complexes | 397 |
22 The Barbier Reaction | 405 |
23 Grignard Reagents as Bases | 441 |
24 SN2 Versus SN2 | 455 |
Preparation and Reactions | 497 |
26 Formation and Reactions of Substituted 2Butene14diylmagnesium Complexes | 527 |
9 Crystal Structures of Grignard Reagents | 117 |
10 Mechanism of Grignard Reagent Formation | 145 |
11 Mechanisms of Reactions of Grignard Reagents | 219 |
12 StructureReactivity Relationships | 249 |
The Schlenk Equilibrium and Its Effect on Reactivity | 271 |
14 Effect of Trispyrazolylhydroborato Ligation | 291 |
15 Nucleophilic Substitution with Electrophilic Organic Main Group and Transition Metal Species | 307 |
16 Nucleophilic Addition to Unconjugated CC Multiple Bonds | 355 |
O S N P | 361 |
18 Nucleophilic Addition to MetalCarbon Multiple Bonds | 373 |
27 Spiroannulations Using Substituted 2Butene14diylmagnesium Complexes | 539 |
28 Asymmetric Synthesis Using Grignard Reagents | 557 |
29 MetalCatalyzed Reactions | 577 |
30 The Preparation of 11Bimetallics of Magnesium and Zinc | 633 |
31 Alkynyl Grignard Reagents and Their Uses | 645 |
32 Grignard Reagents and Silanes | 667 |
33 ZieglerNatta Catalysis | 677 |
34 Organomagnesium Compounds as Polymerization Initiators | 685 |
Back Cover | 703 |
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多く使われている語句
acetylenic acid addition reaction alcohol aldehydes alkyl allylic amines anion aryl Barbier reaction benzophenone benzyl Bickelhaupt bond Bull carbon carbonyl catalyst Chem chemical chemistry Chern Chim chiral chloride complex conjugated crystal structure cyclic cyclopropyl derivatives di-Grignard reagent diethyl ether dimeric electrophiles enolate Entry esters ethylmagnesium bromide example formed Grignard reaction Grignard reagent Grignard reagent formation halogen hydrolysis intermediate iodide ketones l,4-addition leaving group ligand lithium magnesium surface mechanism methyl methylmagnesium Mg atom MgBr MgBr2 Miginiac mixture molecules monomers Normant nucleophilic addition nucleophilic substitution observed obtained olefins optically active organomagnesium compounds Organomet organometallic Organornet oxidation phenylmagnesium bromide polymer polymerization prepared presence propargyl R. D. Rieke racemic radical ratio react reactions of Grignard reactivity reduction regioselectivity reported Rieke magnesium RMgX Scheme Schlenk equilibrium solution solvent species stereochemistry stereoselectivity steric studies substrates synthesis Table Tetrahedron Lett tetrahydrofuran toluene transition metal vinyl Walborsky yield