Name Reactions: A Collection of Detailed Reaction Mechanisms

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Springer Science & Business Media, 2013/11/11 - 465 ページ
The second edition includes five points of improvement: (a) Additional 16 name reactions have been supplemented; (b) I have corrected typos and a few dubious mechanisms in the first edition. I wish to thank Prof. Rick L. Danheiser of Massa chusetts Institute of Technology and Mr. Yiqian Lian of Michigan State Univer sity for invaluable comments and suggestions. I have also incurred many debts of gratitude to Prof. Brian. M. Stoltz of California Institute of Technology and his students, Eric Ashley, Doug Behenna, Dan Caspi, Neil Garg, Blake Greene, Jeremy May, Sarah Spessard, Uttam Tambar, Raissa Trend, and Ryan Zeidan for proofreading the final draft of the second edition; (c) The references are expanded and updated; (d) A more thorough index has been implemented so the reader may navigate through the book more easily; (e) The short descriptions of name reactions given as mnemonics seem to be helpful to both novices and veterans. As a result, I added the descriptions for most reactions. Finally, I am grateful for permission to use the postage stamps on the inner covers from respective postal authorities, who still retail the copyrights of those stamps. Jack Li Ann Arbor, Michigan, May 2003 Preface to the first edition What's in a name? That which we call a rose by any other name would smell as 1 sweet.
 

目次

Brown hydroboration reaction
53
Bucherer carbazole synthesis
54
Bucherer reaction
56
BuchererBergs reaction
57
BuchnerCurtiusSchlotterbeck reaction
58
Buchner method of ring expansion
59
BuchwaldHartwig CN bond and CO bond formation reactions
60
Burgess dehydrating reagent
61
Kumada crosscoupling reaction
233
Larock indole synthesis
235
Lawessons reagent
236
LeuckartWallach reaction
237
Lieben haloform reaction
238
LiebeskindSrogl coupling
239
Lossen rearrangement
240
Luche reduction
241

CadiotChodkiewicz coupling
62
Cannizzaro dispropotionation reaction
63
Carroll rearrangement
65
CastroStephens coupling
66
Chapman rearrangement
67
Chichibabin amination reaction
68
Chichibabin pyridine synthesis
69
Chugaev reaction
71
CiamicianDennsted rearrangement
72
Claisen condensation
73
Claisen rearrangement
74
ClarkeEschweiler reductive alkylation of amines
76
Clemmensen reduction
77
Combes quinoline synthesis
79
ConradLimpach reaction
81
CookHeilbron thiazole synthesis
82
Cope elimination reaction
83
Cope oxyCope and anionic oxyCope rearrangements
84
CoreyBakshiShibata CBS reduction
86
CoreyChaykovsky reaction
88
CoreyFuchs reaction
90
CoreyKim oxidation
92
CoreyWinter olefin synthesis
93
Cornforth rearrangement
95
Criegee glycol cleavage
96
Criegee mechanism of ozonolysis
97
Curtius rearrangement
98
Dakin oxidation
99
DakinWest reaction
100
Danheiser annulation
102
Darzens glycidic ester condensation
103
Davis chiral oxaziridine reagent
104
de Mayo reaction
105
Demjanov rearrangement
107
DessMartin periodinane oxidation
109
Dieckmann condensation
110
DielsAlder reaction
111
Dienonephenol rearrangement
113
Diлmethane rearrangement
114
Doebner reaction
115
Doebnervon Miller reaction
117
DoeringLaFlamme allene synthesis
119
DornowWiehler isoxazole synthesis
120
Dötz reaction
122
Dowd ring expansion
123
DuttWormall reaction
125
Eglinton reaction
126
Eschenmoser coupling reaction
127
EschenmoserTanabe fragmentation
128
Étard reaction
129
Evans aldol reaction
130
Favorskii rearrangement and QuasiFavorskii rearrangement
132
FeistBénary furan synthesis
134
Ferrier rearrangement
135
Finkelstein reaction
136
FischerHepp rearrangement
137
Fischer indole synthesis
138
FischerSpeier esterification
139
Fleming oxidation
140
Forster reaction
142
FraterSeebach alkylation
144
FriedelCrafts reaction
145
Friedländer synthesis
147
Fries rearrangement
149
FritschButtenbergWiechell rearrangement
151
FujimotoBelleau reaction
152
Fukuyama amine synthesis
153
Gabriel synthesis
155
Gassman indole synthesis
156
GattermannKoch reaction
157
Gewald aminothiophene synthesis
158
Glaser coupling
160
GombergBachmann reaction
161
Gribble indole reduction
162
Gribble reduction of diaryl ketones
163
Grignard reaction
164
Grob fragmentation
166
GuareschiThorpe condensation
168
HajosWiechert reaction
169
HallerBauer reaction
171
Hantzsch pyridine synthesis
172
Hantzsch pyrrole synthesis
174
Haworth reaction
175
Hayashi rearrangement
177
Heck reaction
179
Hegedus indole synthesis
181
HellVolhardtZelinsky reaction
182
Henry reaction nitroaldol reaction
183
Herz reaction
184
Heteroaryl Heck reaction
186
Hiyama crosscoupling reaction
187
HochCampbell aziridine synthesis
189
HodgesVedejs metallation of oxazoles
191
Hofmann rearrangement Hofmann degradation reaction
192
HofmannLöfflerFreytag reaction
193
HofmannMartius reaction ReillyHickinbottom rearrangement
194
Hooker oxidation
196
HornerWadsworthEmmons reaction
198
HoubenHoesch synthesis
200
Hunsdiecker reaction
202
IngManske procedure
203
JacobsenKatsuki epoxidation
204
Jacobsen rearrangement
206
JappKlingemann hydrazone synthesis
208
JuliaLythgoe olefination
209
Kahne glycosidation
211
Keck stereoselective allylation
213
Keck macrolactonization
215
Kemp elimination
217
Kennedy oxidative cyclization
218
Kharasch addition reaction
219
Knöevenagel condensation
220
Knorr pyrrole synthesis
222
Koch carbonylation reaction KochHaaf carbonylation reaction
223
KoenigKnorr glycosidation
225
Kolbe electrolytic coupling
226
KolbeSchmitt reaction
227
Kostanecki reaction
228
Krapcho decarboxylation
230
Kröhnke reaction pyridine synthesis
231
McFadyenStevens reduction
242
McMurry coupling
244
Madelung indole synthesis
245
Mannich reaction
246
Marshall boronate fragmentation
248
Martins sulfurane dehydrating reagent
249
MasamuneRoush conditions
251
Meerwein arylation
253
MeerweinPonndorfVerley reduction
254
Meinwald rearrangement
255
Meisenheimer complex
256
Meisenheimer rearrangement
258
MeyerSchuster rearrangement
259
Michael addition
260
MichaelisArbuzov phosphonate synthesis
261
Midland reduction
262
MillerLoudonSnyder nitrile synthesis
263
MislowEvans rearrangement
264
Mitsunobu reaction
265
Miyaura boration reaction
266
Moffatt oxidation
267
MorganWalls reaction PictetHubert reaction
269
MoriBan indole synthesis
270
Morin rearrangement
272
Mukaiyama aldol reaction
274
Mukaiyama esterification
275
MyersSaito cyclization
277
Nametkin rearrangement retropinacol rearrangement
279
Nazarov cyclization
280
Neber rearrangement
281
Nef reaction
282
Negishi crosscoupling reaction
283
Nenitzescu indole synthesis
284
Nicholas reaction
286
Noyori asymmetric hydrogenation
287
NozakiHiyamaKishi reaction
289
Oppenauer oxidation
290
Orton rearrangement
291
Overman rearrangement
293
PaalKnorr furan synthesis
294
PaalKnorr pyrrole synthesis
295
Parham cyclization
296
Passerini reaction
298
PaternoBüchi reaction
299
PausonKhand cyclopentenone synthesis
300
Payne rearrangement
302
Pechmann condensation coumarin synthesis
303
Pechmann pyrazole synthesis
304
Perkin reaction cinnamic acid synthesis
305
Perkow vinyl phosphate synthesis
307
Peterson olefination
308
PfauPlattner azulene synthesis
310
Pfitzinger quinoline synthesis
311
PictetGams isoquinoline synthesis
312
PictetSpengler tetrahydroisoquinoline synthesis
314
Pinacol rearrangement
315
Pinner synthesis
316
Polonovski reaction
317
PolonovskiPotier rearrangement
319
PomeranzFritsch reaction
320
Prévost transdihydroxylation
322
Prilezhaev reaction
323
Prins reaction
324
Pschorr ring closure
325
Pummerer rearrangement
327
RambergBäcklund olefin synthesis
328
Reformatsky reaction
329
Regitz diazo synthesis
330
ReimerTiemann reaction
332
Reissert reaction aldehyde synthesis
334
Riley oxidation selenium dioxide oxidation
336
Ringclosing metathesis RCM using Grubbs and Schrock catalysts
337
Ritter reaction
339
Robinson annulation
340
RobinsonSchöpf reaction
341
Rosenmund reduction
343
Roush allylboronate reagent
344
Rubottom oxidation
345
Rupe rearrangement
346
Rychnovsky polyol synthesis
347
Sakurai allylation reaction HosomiSakurai reaction
349
Sandmeyer reaction
351
Sarett oxidation
352
Schiemann reaction BalzSchiemann reaction
354
Schlosser modification of the Wittig reaction
355
Schmidt reaction
356
Schmidts trichloroacetimidate glycosidation reaction
357
Scholl reaction
359
Schöpf reaction
361
SchottenBaumann reaction
362
Shapiro reaction
363
Sharpless asymmetric amino hydroxylation
364
Sharpless asymmetric epoxidation
366
276
375
280
381
284
387
288
393
293
399
297
405
301
411
306
418
310
424
315
431
318
437
Wittig reaction
438
12Wittig rearrangement
439
23Wittig rearrangement
440
WohlZiegler reaction
441
Wolff rearrangement
443
WolffKishner reduction
444
Woodward cisdihydroxylation
445
Wurtz reaction
446
Yamada coupling reagent
447
Yamaguchi esterification
448
Zaitsev elimination
450
Zincke reaction
451
Zinin benzidine rearrangement semidine rearrangement
453
10
455
McLafferty rearrangement 243
460
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