The Chemistry of Transition Metal Carbides and NitridesSpringer Science & Business Media, 2012/12/06 - 536 ページ This book arose from a symposium titled 'Transition Metal Carbides and Nitrides: Preparation, Properties, and Reactivity' organized by Jae Sung Lee, Masatoshi Nagai and myself. The symposium was part of the 1995 Congress of Pacific Rim Chemical Societies, held in Honolulu, Hawaii between December 17-22, 1995. The meeting was the first major conference to exclusively address the theme of metal carbides and nitrides, and brought together many of the major researchers in the field. Over 50 scientists and engineers reported their latest findings in five sessions of presentations and discussions. The book closely follows the topics covered in the conference: Theory of bonding Structure and composition Catalytic properties Physical properties New methods of preparation Spectroscopy and microscopy The book is unique in its coverage. It provides a general introduction to the properties and nature of the materials, but also covers their latest applications in a wide variety of fields. It should thus be of interest to both experts and nonexperts in the fields of material science, solid-state chemistry, physics, ceramics engineering, and catalysis. The first chapter gives an overview, and many of the chapters provide summaries of advanced topics. All contributions were peer-reviewed. |
目次
1 | |
9 | |
Surface molybdenum species and acid sites | 17 |
54 | 19 |
Study of the isomerization of C6 and C6+ alkanes over | 20 |
71 | 26 |
Application of transition metal carbides and nitrides | 28 |
Acknowledgment | 50 |
References | 250 |
Synthesis of thin films of Cr Mo and W carbides and nitrides | 274 |
Singlesource precursors for the chemical vapor | 290 |
Acknowledgments | 309 |
Acknowledgments | 326 |
111 | 332 |
Acknowledgements | 343 |
References | 361 |
31 | 64 |
37 | 75 |
41 | 90 |
THEORY | 107 |
Fermi surface of hexagonal tungsten carbide | 121 |
Acknowledgements | 133 |
Acknowledgments | 152 |
Magnetic properties of rare earthiron compounds | 191 |
Acknowledgments | 213 |
References | 231 |
Combustion synthesis of transition metal nitrides | 233 |
Acknowledgments | 372 |
Acknowledgments | 396 |
Synthesis and catalytic properties of tungsten | 414 |
SPECTROSCOPY AND MICROSCOPY | 426 |
114 | 438 |
Acknowledgments | 453 |
Study of the Auger metal peak of carbides | 473 |
488 | |
Carbide formation during activation of iron | 511 |
533 | |
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activity alloys ammonia atoms band bonding calculated carbides and nitrides carbon carbonitride Catal catalyst cemented carbides Chem chemical coatings composition compounds decomposition density deposition desorption diffraction diffusion coefficient electron energy equation experimental Fermi energy Fermi surfaces films formation H₂ heating high temperature hydrocarbons hydrogen increase interactions isomerization lattice layers magnetic magnetite materials mechanism metal nitrides metalcutting Mo₂C molecular molybdenum MoO3 N₂ nitrogen nitrogen pressure nonmetal observed orbitals oxide oxycarbide oxygen parameters particle peak Phys plane powder precursor properties ratio reaction reactive S.T. Oyama samples shows Single Crystal XRD sintering solid phase dilution solid solutions spectra sputtering stoichiometric structure substrate superconducting surface area synthesis Table ternary nitrides thermal titanium titanium nitride transition metal transition metal carbides trigonal trigonal planar tungsten carbide values vanadium vanadium carbide vaporization Xecvc