Advances in Organometallic Chemistry, 第 50 巻Elsevier, 2004/02/10 - 470 ページ Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. The widely acclaimed serial Advances in Organometallic Chemistry contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.
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目次
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Chapter 2 Transition Metal Complexes Bearing a Phosphenium Ligand | 107 |
Chapter 3 Synthesis of Organosilicon Compounds by New Direct Reactions | 145 |
Chapter 4 Transition Metal Complexes Containing AllCarbon Ligands | 179 |
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多く使われている語句
29Si chemical shifts 29Si NMR affords alkyl chlorides alkyne American Chemical Society analogous angles anion bands binuclear bond lengths bridging C–C bond C–C separation C2 ligand C2 unit carbide carbon chain catalyst cationic cationic phosphenium complex chelate Chem chemical shifts chemistry chloromethyl)silanes cluster cmÀ1 complexes containing compounds coordination coupling constants crystal structure cumulenic decomposition derivatives dianion diastereomers direct reaction donor dppe electron elemental silicon ethyne exchange formation formed fragment geometry give groups hexacoordinate hydrogen chloride interactions intermediate ionization isomer Kalikhman kcal/mol ligand metal centers methyl chloride migration mixture moiety Molecular structure molecules N-methyl NMR spectra observed obtained orbitals Organomet Organometallics oxidation pentacoordinate phosphine phosphorus polymer polymeric PPh3 processes reaction of elemental reacts Reproduced with permission resonances Scheme signals silicon siliconium silylene solution solvents species stable substituents Table temperature transition metal trichlorosilane trigonal yield zwitterionic